文献类型：期刊文献

英文题名：Synthesis and characterization of new highly soluble and thermal-stable perylene-PPV copolymers containing triphenylamine moiety

作者：Hua, Jianli[1,2]; Meng, Fanshun[1]; Li, Jin[1]; Ding, Fang[1]; Fan, Xin[1]; Tian, He[1]

机构：[1]E China Univ Sci & Technol, Adv Mat Lab, Shanghai 200237, Peoples R China;[2]E China Univ Sci & Technol, Inst Fine Chem, Shanghai 200237, Peoples R China;[3]Jiangxi Normal Univ, Dept Chem, Nanchang 330027, Peoples R China

年份：2006

卷号：42

期号：10

起止页码：2686

外文期刊名：EUROPEAN POLYMER JOURNAL

收录：;EI(收录号：20063910137249);WOS:【SCI-EXPANDED(收录号:WOS:000241460100054)】；

语种：英文

外文关键词：perylene; poly(p-phenylenevinylene); triphenylamine; synthesis; high solubility

摘要：Three new copolymers containing poly(p-phenylenevinylene) (PPV) and triphenylamine (TPA) moieties carrying N(n-butyl)-N'-ethoxy-1,6,7,12-tetra-(4-tert-butylphenoxy)-3,4,9, 10-perylenetetracarboxylic bisimide (PERY) pendant groups were successfully synthesized by Wittig condensation. The molar percentage of perylene pendants in copolymers was controlled by tuning the initial feed ratio of the perylene-bisaldehyde monomer. The structures and properties of three copolymers were characterized and evaluated by FT-IR, NMR, UV, FL, and photovoltaic analyses. The copolymers were highly soluble in conventional solvents such as toluene, CHCl3, THF, DMF, etc., and they were thermally stable (>= 396 degrees C). Three copolymers have emission spectra with characteristic features of the perylene unit, however, and their luminescence are largely quenched with the increasing amount of PERY units in copolymers. The photophysical study in solution has shown that singlet-singlet energy transfers from PPV backbone to perylene in the copolymers. The photovoltaic devices ITO/PEDOT:PSS/copolymers/Ba/Al were fabricated, and the energy conversion efficiency of the device is only about 0.0005%, further indicating that an efficient energy transfer has taken place from PPV to perylene in the copolymers. (c) 2006 Elsevier Ltd. All rights reserved.