文献类型：期刊文献

英文题名：Catalytic production of 2,5-dimethylfuran from 5-hydroxymethylfurfural over Ni/Co3O4 catalyst

作者：Yang, Panpan[1];Cui, Qiqi[1];Zu, Yanhong[1];Liu, Xiaohui[1];Lu, Guanzhong[1];Wang, Yanqin[1]

机构：[1]E China Univ Sci & Technol, Res Inst Ind Catalysis, Shanghai Key Lab Funct Mat Chem, Shanghai 200237, Peoples R China

年份：2015

卷号：66

起止页码：55

外文期刊名：CATALYSIS COMMUNICATIONS

收录：;EI(收录号：20151300679022);WOS:【SCI-EXPANDED(收录号:WOS:000353736600013)】；

基金：This project was supported financially by the NSFC (No. 21101063 and 21273071), the Science and Technology Commission of Shanghai Municipality (13520711400, 13JC1401902, 10dz2220500) and the Fundamental Research Funds for the Central Universities, China.

语种：英文

外文关键词：Ni/Co3O4; Hydrogenolysis; 5-Hydroxymethylfurfural; 2,5-Dimethylfuran

摘要：Ni/Co3O4, a non-precious metal catalyst was used for the first time in the catalytic conversion of 5-hydroxymethylfurfural (HMF) to 2,5-dimethylfuran (DMF). Under relatively mild conditions (130 degrees C, 1.0 MPa), as high as 76% yield of DMF was achieved. The addition of Ni not only prevented the formation of by-products, which happened due to the over-reduction of Co3O4 during hydrogenolysis, but also enhanced the reusability of Ni/Co3O4, and the catalyst could be reused for 6 times without loss of activity. Crown Copyright (C) 2015 Published by Elsevier B.V. All rights reserved.