文献类型：期刊文献

英文题名：Synthesis and Characterization of Complex of Glycyl-L-Glutamine and Bismuth Trichloride

作者：Luan, Shaorong[1,2];Zhu, Yihua[1];Jia, Yuqing[3]

机构：[1]E China Univ Sci & Technol, Key Lab Ultrafine Mat, Minist Educ, Sch Mat Sci & Engn, Shanghai 200237, Peoples R China;[2]E China Univ Sci & Technol, Res Ctr Anal & Test, Sch Chem & Mol Engn, Shanghai 200237, Peoples R China;[3]E China Univ Sci & Technol, Dept Chem, Sch Chem & Mol Engn, Shanghai 200237, Peoples R China

年份：2008

卷号：15

期号：10

起止页码：1094

外文期刊名：PROTEIN AND PEPTIDE LETTERS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000260058100010)】；

基金：The authors gratefully acknowledge the National Natural Science Foundation of China (20676038) and Key Project of Science and Technology for Ministry of Education (107045) for financial supports.

语种：英文

外文关键词：Peptide complex; bismuth trichloride; glycyl-L-glutamine; solid-solid reaction; synthesis; characterizations

摘要：A novel peptide complex was synthesized by a solid-solid reaction of glycyl- L- glutamine monohydrate and bismuth trichloride powders. The formula of the complex is ( BiCl3)(2)[ NH2CH2CONHCH( COOH)CH2CH2COOH center dot H2O](3). The crystal structure of the complex belongs to monoclinic system with the lattice parameters: a = 0.6914 nm, b = 0.7378 nm, c = 1.0005 beta = 194.1 degrees. The characterization results of IR, Raman spectra and thermal analysis show that complex is dimer and unidentate coordination. Each bismuth atom and three chlorine atoms are coplanar in the complex.