文献类型：期刊文献

英文题名：Palladium-catalyzed asymmetric allylic substitutions in the presence of chiral phosphine-imine type ligands

作者：Sun, Yin-Wei[2,3];Jiang, Jia-Jun[2,3];Zhao, Mei-Xin[2,3];Wang, Fei-Jun[2,3];Shi, Min[1,2,3]

机构：[1]Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China;[2]E China Univ Sci & Technol, Key Lab Adv Mat, Shanghai 200237, Peoples R China;[3]E China Univ Sci & Technol, Inst Fine Chem, Sch Chem & Mol Engn, Shanghai 200237, Peoples R China

年份：2011

卷号：696

期号：15-16

起止页码：2850

外文期刊名：JOURNAL OF ORGANOMETALLIC CHEMISTRY

收录：;EI(收录号：20112714115414);WOS:【SCI-EXPANDED(收录号:WOS:000292187800014)】；

基金：Financial support from the Shanghai Municipal Committee of Science and Technology (08dj1400100-2), National Basic Research Program of China (973)-2010CB833302, the Fundamental Research Funds for the Central Universities and the National Natural Science Foundation of China for financial support (21072206, 20472096, 20872162, 20672127, 20821002 and 20732008) is greatly acknowledged.

语种：英文

外文关键词：Asymmetric allylic substitution; Palladium-catalyzed; Phosphine-imine type ligands

摘要：Chiral bidentate phosphine-imine type ligand L9 is fairly effective in the asymmetric allylic substitution of 1,3-diphenylpropenyl acetate with dimethyl malonate to give the corresponding adduct in moderate yield and good ee. (C) 2011 Elsevier B.V. All rights reserved.