文献类型：期刊文献

中文题名：新型催化剂上甲苯、丙烯、一氧化碳催化燃烧反应动力学

英文题名：CATALYTIC COMBUSTION OF TOLUENE,PROPYLENE AND CARBON MONOXIDE AND KINETICS

作者：应卫勇[1];廖仕杰[1];房鼎业[1];Kameyama Hideo[2]

机构：[1]华东理工大学化学工程系,上海200237;[2]东京农工大学化学工程系,日本东京1840012

年份：2002

卷号：53

期号：10

起止页码：1051

中文期刊名：化工学报

外文期刊名：CIESC Journal

收录：CSTPCD;;EI(收录号：2003037327799);Scopus;北大核心:【北大核心2000】；CSCD:【CSCD2011_2012】；

语种：中文

中文关键词：催化剂;甲苯;丙烯;一氧化碳;催化燃烧;反应动力学;化工厂;废气治理;有机污染物

外文关键词：Carbon monoxide;Catalysts;Combustion;Propylene;Reaction kinetics;Waste treatment

摘要：以甲苯、丙烯、一氧化碳为代表物研究了在金属壁与催化层一体化催化剂上的催化燃烧 ,假设吸附解离态的氧与吸附态的反应物反应建立了催化燃烧反应动力学模型 ,得到了甲苯、丙烯、一氧化碳混合物在空气中催化燃烧反应动力学方程 .
The catalytic combustion of toluene, propylene and carbon monoxide is investigated over a catalyst with metallic wall and catalytic layer. The catalyst is prepared by anodic oxidation of aluminium, hydration treatment and impregnation of a chloroplatinic acid hexahydrate solution. It has the advantages of high activity, easiness to form various shapes, and low pressure drop. The catalytic combustion experiments of the individual component and the mixtures of toluene, propylene and carbon monoxide are studied, and the inhibition effects are observed from the experimental data. The mechanism that reactant A is absorbed and reacts with dissociatively adsorbed oxygen is adopted. The kinetic models are obtained for each component in the mixtures.