文献类型：期刊文献

英文题名：Catalytic transfer hydrogenation/hydrogenolysis of 5-hydroxymethylfurfural to 2,5-dimethylfuran over Ni-Co/C catalyst

作者：Yang, Panpan[1];Xia, Qineng[1];Liu, Xiaohui[1];Wang, Yanqin[1]

机构：[1]East China Univ Sci & Technol, Res Inst Ind Catalysis, Sch Chem & Mol Engn, Key Lab Adv Mat, Shanghai 200237, Peoples R China

年份：2017

卷号：187

起止页码：159

外文期刊名：FUEL

收录：;EI(收录号：20164202907718);WOS:【SCI-EXPANDED(收录号:WOS:000386187100018)】；

基金：The research was sponsored financially by the National Natural Science Foundation of China (Nos. 91545103 and 21273071).

语种：英文

外文关键词：Ni-Co/C; Catalytic transfer hydrogenation; 5-Hydroxymethylfurfural; 2,5-Dimethylfuran; Formic acid

摘要：Catalytic transfer hydrogenation/hydrogenolysis of 5-hydroxymethylfurfural (HMF) to valuable chemicals, 2,5-dimethylfuran (DMF), is realized over a carbon supported nickel-cobalt catalyst with formic acid as hydrogen donor. The highest DMF yield, 90.0%, is achieved at 210 degrees C under self-generated pressure. A reaction route involving 5-methylfurfural (5-MF) instead of 2,5-bis(hydromethyl)furan (BHMF) as an intermediate has been investigated, which is different from that when H-2 is used as hydrogen source in previous reports. The influence of the amount of formic acid is investigated on the conversion of HMF and the yield of DMF. The effectiveness of this strategy has also been used for the conversion of furfural to 2-methylfuran, another valuable chemicals. (C) 2016 Elsevier Ltd. All rights reserved.