文献类型：期刊文献

英文题名：High-performance PdNi alloy structured in situ on monolithic metal foam for coalbed methane deoxygenation via catalytic combustion

作者：Zhang, Qiaofei[1];Wu, Xin-Ping[2,3];Zhao, Guofeng[1];Li, Yakun[1];Wang, Chunzheng[1];Liu, Ye[1];Gong, Xue-Qing[2,3];Lu, Yong[1]

机构：[1]East China Normal Univ, Shanghai Key Lab Green Chem & Chem Proc, Sch Chem & Mol Engn, Shanghai 200062, Peoples R China;[2]E China Univ Sci & Technol, Key Lab Adv Mat, Ctr Computat Chem, Shanghai 200237, Peoples R China;[3]E China Univ Sci & Technol, Res Inst Ind Catalysis, Shanghai 200237, Peoples R China

年份：2015

卷号：51

期号：63

起止页码：12613

外文期刊名：CHEMICAL COMMUNICATIONS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000358520200025)】；

基金：This work was financially supported by the "973 program'' (2011CB201403) from the MOST of China, and the NSF of China (21473057, 21322307, 21273075, U1462129).

语种：英文

摘要：A monolithic Ni-foam@PdNi(alloy) catalyst is tailored for coalbed methane deoxygenation via galvanically depositing Pd nanoparticles on a Ni-foam surface followed by in situ activation. Experimental and theoretical studies unanimously reveal that the in situ formed PdNi alloy contributes to high activity/selectivity, good stability and oscillation elimination.