文献类型：期刊文献

中文题名：TiO_2-SiO_2二维大孔薄膜的制备及其光催化活性研究

英文题名：Preparation and Photocatalytic Study of TiO_2-SiO_2 Macroporous Film

作者：杨小龙[1];潘月[1];邢明阳[1];张金龙[1]

机构：[1]华东理工大学精细化工研究所,上海200237

年份：2015

卷号：33

期号：5

起止页码：383

中文期刊名：影像科学与光化学

外文期刊名：Imaging Science and Photochemistry

收录：CSTPCD;;Scopus;北大核心:【北大核心2014】；CSCD:【CSCD2015_2016】；

基金：国家自然科学基金(21203062;21377038;21173077;21237003);国家重点基础研究发展规划973项目(2013CB632403);高等学校博士学科点专项科研基金(20120074130001);中央高校基本科研业务费(22A201514021)资助

语种：中文

中文关键词：大孔薄膜;二氧化钛;聚苯乙烯小球;真空活化;光催化

外文关键词：macroporous films; titania; polystyrene spheres; vacuum activation; photocatalysis

摘要：本文采用改进的溶胶-凝胶法制备了具有锐钛矿晶型结构和较小晶粒尺寸的TiO2-SiO2溶胶,并以聚苯乙烯(PS)小球为模板,采用旋涂法制备了新型大孔TiO2-SiO2复合薄膜,探究了煅烧温度、不同硅钛比以及溶胶添加量对所制备的大孔薄膜形貌及光催化活性的影响,并考察了该薄膜真空活化前后(Ti 3+掺杂后)在紫外及模拟太阳光下光催化降解有机污染物罗丹明B的活性。通过Raman、DRS、SEM、EPR等方法对薄膜进行表征,发现制备的复合薄膜具有高透明度、良好附着力及优异的光催化活性。
In this work,the TiO2-SiO2 sol was prepared by a modified sol-gel method,which exhibited the anatase and small crystal size.And then the macroporous TiO2-SiO2 film was synthesized by using polystyrene spheres as the template and TiO2-SiO2 sol as the precursor,viathe spinning-coating combined with calcination technology.We investigated the impact of calcination temperature,Ti/Si ratio and concentration of sol on the microstructure and photocatalytic activity of macroporous TiO2-SiO2 film.We also studied the UV/solar light photcoatalytic activity for the degradation of rhodamin B over the composite film after a vacuum activation treatment.The RAMAN,DRS,SEM,EPR,and other characterizations were used to study a serials of TiO2-SiO2 films,as a result,the as-prepared film showed a good transparent property,excellent adhesion and photcatalytic activity.