文献类型：期刊文献

中文题名：CO CO_2 H_2 N_2在液体石蜡油中溶解度的测定

英文题名：Investigation on Solubility of CO, CO_2, H_2 and N_2 In Saxoline

作者：张海涛[1];应卫勇[1];房鼎业[1]

机构：[1]华东理工大学化工学院,上海200237

年份：2003

卷号：28

期号：4

起止页码：59

中文期刊名：天然气化工—C1化学与化工

外文期刊名：Natural Gas Chemical Industry

收录：CSTPCD;;北大核心:【北大核心2000】；CSCD:【CSCD_E2011_2012】；

语种：中文

中文关键词：合成气;液体石蜡油;催化剂;平衡溶解度

外文关键词：syngas; saxoline; catalyst; equilibrium solubility

摘要：利用高压搅拌反应釜,基于气体等容吸收降压原理,在合成气制二甲醚的反应条件范围内,测定了CO、CO2、H2、N2在含有细颗粒固体催化剂的液体石蜡油中的溶解度。实验结果表明,气体的溶解度是温度与气体分压的函数,回归了溶解度与温度、压力的关联式,为工业反应器设计提供了基础数据。
The solubility of CO, CO2, H2 and N2 was measured at the reactive condition of dimethyl ether synthesis from syngas in the stirring vessel The solvent included the catalyst of methanol synthesis and methanol dehydration Experiments were carried out based on the theory of isopyknic gas absorption The data showed that the solubility of the gases was the functions of temperature and partial pressure The experimental formula of solubility, temperature and pressure was evaluated These were the essential data for the industrialization of the slurry reactor