文献类型：期刊文献

中文题名：氢氧化镁碳化过程研究

英文题名：Carbonization Process of Magnesium Hydroxide

作者：陈闵敏[1,2];孙玉柱[1,2,3];宋兴福[1,2];唐智新[2];吴刚[2]

机构：[1]华东理工大学资源(盐湖)过程工程教育部工程研究中心,上海200237;[2]河北省海水淡化技术创新中心,河北唐山063200;[3]上海污染控制与生态安全研究院,上海200092

年份：2022

卷号：48

期号：5

起止页码：600

中文期刊名：华东理工大学学报（自然科学版）

外文期刊名：Journal of East China University of Science and Technology

收录：Scopus;北大核心:【北大核心2020】；CSCD:【CSCD_E2021_2022】；

基金：国家重点研发计划(2019YFC0408204,2016YFC0401203);国家自然科学基金(U1507105);上海市优秀学术/技术带头人计划资助(18XD1424600)。

语种：中文

中文关键词：氢氧化镁;碳化法;二氧化碳;碳酸氢镁

外文关键词：magnesium hydroxide;carbonization method;carbon dioxide;magnesium bicarbonate

摘要：研究了氢氧化镁碳化制备碳酸氢镁的过程,考察了液固比(氢氧化镁浆料中水与氢氧化镁质量之比)、浆料温度、二氧化碳气速、搅拌速度以及氢氧化镁原料差异对碳化过程的影响。结果表明:在常温常压下,液固比为40、二氧化碳气速为400 mL/min、搅拌速度为300 r/min时碳化效果最佳;氢氧化镁粒度越小,分散性越好,对碳化过程越有利;分析纯氢氧化镁与自制氢氧化镁碳化所得碳酸氢镁溶液中镁离子浓度分别为0.315 mol/L以及0.203 mol/L;同时对碳化过程氢氧化镁缩壳模型进行了简要探讨,碳化过程拟合结果呈现出较好的线性。
With the rapid progress of seawater desalination technology,concentrated brine has not been effectively used due to the lack of mature development and treatment process.Direct emissions of concentrated brine are seriously harmful to the ecological environment.At the same time,massive emissions of carbon dioxide have exacerbated the greenhouse effect.Aiming at the resource utilization of concentrated brine and carbon dioxide,combined with the previous research basis of using calcium hydroxide as the precipitant to prepare magnesium hydroxide,this paper proposes a carbonization technical process to prepare magnesium bicarbonate using magnesium hydroxide as the precursor from low magnesium systems.The research focused on the carbonization process of magnesium hydroxide,investigating the influence of liquid-solid ratio,temperature,carbon dioxide gas velocity,stirring speed,and raw material difference on the carbonization process,and monitoring the change of calcium and magnesium ion concentration and pH value during the carbonization process.It was found that under room temperature and atmospheric pressure,the carbonization effect was the best when the liquid-solid ratio was 40,the carbon dioxide gas velocity was 400 mL/min,and the stirring speed was 300 r/min,the concentration of Mg^(2+) in the carbonization solution from magnesium hydroxide(AR)was 0.315 mol/L and there existed no Ca^(2+) ,the concentration of Mg^(2+) in the carbonization solution from self-made magnesium hydroxide was 0.203 mol/L,the concentration of Ca^(2+) was 3.2×10^(?4) mol/L,calcium impurities were basically separated.The particle size and dispersion of magnesium hydroxide had a significant impact on the carbonization effect,smaller particle size and better dispersion promoted the carbonization process.The shrinking core model of magnesium hydroxide was briefly discussed at the same time,the fits of the carbonization process at different slurry temperatures showed good linearity.