文献类型：期刊文献

中文题名：利用变阱宽方阱链流体状态方程计算1：1电解质溶液热力学性质

英文题名：Calculation of thermodynamic properties for 1:1 electrolyte solutions by square-well chain fluid with variable range-based equation of state

作者：罗志林[1];李进龙[2];彭昌军[1];刘洪来[1]

机构：[1]华东理工大学化学系,化学工程联合国家重点实验室,上海200237;[2]华东理工大学信息科学与工程学院,上海200237

年份：2014

卷号：65

期号：1

起止页码：39

中文期刊名：化工学报

外文期刊名：CIESC Journal

收录：CSTPCD;;EI(收录号：20141117453660);Scopus;北大核心:【北大核心2011】；CSCD:【CSCD2013_2014】；

基金：国家自然科学基金项目(21136004,21276073);国家重点基础研究发展计划项目(2009CB219902);中央高校基本科研业务费(222201313001);上海市自然科学基金项目(13ZR1411300)~~

语种：中文

中文关键词：电解质水溶液;状态方程;热力学性质;汽液平衡

外文关键词：aqueous electrolyte solution; equation of state; thermodynamic properties; vapor liquid equilibria

摘要：将变阱宽方阱链流体状态方程拓展到1:1强电解质水溶液热力学性质的计算中,通过关联溶液的平均离子活度系数和溶剂的渗透系数得到了22种离子的链节直径和方阱能量参数,40余种电解质溶液的平均离子活度系数和溶剂渗透系数的总平均相对偏差分别为6.03%和5.83%。计算结果表明,建立的电解质型状态方程可以满意预测电解质溶液的密度和宽广温度下溶液的蒸气压,总体平均相对偏差分别为0.22%和4.69%。进一步说明模型参数的可靠性。
An equation of state （EOS） for square-well chain fluids with variable range was applied to calculate thermodynamic properties of 1：1 aqueous electrolyte solutions. The segment diameter and dispersive energy parameter for 22 ions were fitted by experimental data of the mean ionic activity coefficient and osmotic coefficient of more than 40 aqueous electrolyte solutions, with overall average deviations of 6.03% and 5.83%, respectively. The results showed that the EOS can satisfactorily predict the density of aqueous electrolyte solutions and vapor liquid equilibrium of aqueous electrolyte solutions in wide range of temperature with overall average deviations of 0.22% and 4.69%, respectively. The overall average deviations of the prediction proves the reliability of the model parameters.