文献类型：期刊文献

英文题名：Rapid degradation of methylene blue in a novel heterogeneous Fe3O4@rGO@TiO2-catalyzed photo-Fenton system

作者：Yang, Xiaoling[1];Chen, Wei[1];Huang, Jianfei[1];Zhou, Ying[1];Zhu, Yihua[1];Li, Chunzhong[1]

机构：[1]E China Univ Sci & Technol, Sch Mat Sci & Engn, Key Lab Ultrafine Mat, Minist Educ, Shanghai 200237, Peoples R China

年份：2015

卷号：5

外文期刊名：SCIENTIFIC REPORTS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000355523400001)】；

基金：This work was supported by the National Natural Science Foundation of China (21471056, 21236003, 21206042, and 21176083), the Basic Research Program of Shanghai (13NM1400700, 13NM1400701), and the Fundamental Research Funds for the Central Universities.

语种：英文

摘要：Herein, a ternary nanocomposite with TiO2 nanoparticles anchored on reduced graphene oxide (rGO)-encapsulated Fe3O4 spheres (Fe3O4@rGO@TiO2) is presented as a high efficient heterogeneous catalyst for photo-Fenton degradation of recalcitrant pollutants under neutral pH. Fe3O4@rGO@ TiO2 was synthesized by depositing TiO2 nanoparticles on the surface of the Fe3O4 spheres wrapped by graphene oxide (GO) which was obtained by an electrostatic layer-by-layer method. This as-prepared catalyst reflected good ferromagnetism and superior stability which makes it convenient to be separated and recycled. Due to the synergic effects between the different components composed the catalyst, swift reduction of Fe3+ can be achieved to regenerate Fe2+. Fe3O4@rGO@TiO2 exhibited enhancing catalytic activity for the degradation of azo-dyes compared with Fe3O4, Fe3O4@SiO2@ TiO2 or SiO2@rGO@TiO2, further conforming the rapid redox reaction between Fe2+ and Fe3+. All these merits indicate that the composite catalyst possesses great potential for visible-light driven destruction of organic compounds.