文献类型：期刊文献

英文题名：Manipulating the charge transport via incorporating a cobalt bridge into a single-molecule junction

作者：Ma, Chaoqi[1];Li, Yunpeng[1];Tang, Ajun[1];Wang, Rui[1];Li, Yingjie[1];Li, Zhi[1];Yang, Jiawei[1];Li, Hongxiang[1]

机构：[1]East China Univ Sci & Technol, Feringa Nobel Prize Scientist Joint Res Ctr, Frontiers Sci Ctr Materiobiol & Dynam Chem, Sch Chem & Mol Engn,Key Lab Adv Mat,Inst Fine Chem, Shanghai 200237, Peoples R China

年份：2024

卷号：26

期号：3

起止页码：1608

外文期刊名：PHYSICAL CHEMISTRY CHEMICAL PHYSICS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:001128732200001)】；

基金：This work was supported by the National Natural Science Foundation of China (grants 22075080, 52273176, 21875279), the Shanghai Municipal Science and Technology Major Project (grant 2018SHZDZX03), the Fundamental Research Funds for the Central Universities, and East China University of Science and Technology.

语种：英文

摘要：Cobalt-bridged organometallic molecular wires (p-Co-p, p-Co-m and m-Co-m) are synthesized, and their charge transport properties are studied. The experimental results show that the quantum interference (QI) effects of cobalt-bridged organometallic wires are determined by the anchoring group. Interestingly, the cobalt-bridge reduces the conductance of the junctions and tunes the QI effect of the wires. These results demonstrate the unique property of metal-bridged organometallic molecular wires and their potential applications in molecular electronics.