文献类型：期刊文献

英文题名：A 4-MeO-TEMPO, PEG-NO₂ and HCl Catalytic System for Highly Efficient Aerobic Oxidation of Alcohols

作者：Tao, Jianwei[1];Lu, Qiongqiong[1];Chu, Changhu[1];Liu, Renhua[1];Liang, Xinmiao[1,2]

机构：[1]E China Univ Sci & Technol, Shanghai 200237, Peoples R China;[2]Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

年份：2010

期号：23

起止页码：3974

外文期刊名：SYNTHESIS-STUTTGART

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000284535900007)】；

基金：We acknowledge the financial support from National High Technology Research and Development Program of China (863 Program) (No. 2008AA06Z306) and the National Natural Science Foundation of China (No. 21072055)

语种：英文

外文关键词：alcohol oxidation; PEG-NO2; 4-MeO-TEMPO; dioxygen; efficient

摘要：A combination of 4-MeO-TEMPO/PEG-NO2/HCl for catalytic aerobic oxidation of alcohol is described. A wide range of alcohols was efficiently oxidized to the corresponding carbonyl compounds by using this oxidation system and the turnover number (TON) for benzyl alcohol oxidation reached up to 56000.