文献类型：期刊文献

中文题名：反应型乳化剂的合成及其在乳液聚合中的应用

英文题名：Synthesis of reactive emulsifier and its application in emulsion polymerization

作者：万波[1];王得宁[2]

机构：[1]上海威肯化学品有限公司,上海200052;[2]华东理工大学材料学院,上海200237

年份：2003

卷号：26

期号：2

起止页码：94

中文期刊名：合成橡胶工业

外文期刊名：China Synthetic Rubber Industry

收录：CSTPCD;;Scopus;北大核心:【北大核心2000】；CSCD:【CSCD_E2011_2012】；

语种：中文

中文关键词：反应型乳化剂;合成;乳液聚合;应用;可聚合乳化剂;马来酸酐单酯硫酸钠;马来酸酐单酯磺酸钠

外文关键词：polymerizable emulsifier;reactive emulsifier;monomaleate sulfate;mono maleate sulfonate;emulsion polymerization

摘要：合成了2类可聚合乳化剂马来酸酐单酯硫酸钠和马来酸酐单酯磺酸钠,测定了产物的纯度和临界胶束浓度,研究了它们在苯乙烯/丙烯酸丁酯/丙烯酸三元乳液聚合中的转化率。以十二烷基硫酸钠为参照物,用可聚合乳化剂制备的乳液对电解质的稳定性有很大的提高,干胶膜的耐水性和拉伸强度得到了显著改善。
Two kinds of polymerizable emulsifiers,monomaleate sulfate and mono ma leate sulfonate,were synthesized,and their purity,critical micelle concentration and conversion in the emulsion copolymerization of styrene/butyl acrylate/acryl ic acid system were measured.In comparison with sodium dodecyl sulfate,the stabi lity against electrolyte and water of emulsion prepared by polymeriable emulsifi ers were clearly improved,and the extension strength was also modified obviously .