文献类型：期刊文献

英文题名：Monodispersed gold nanoparticles supported on a zirconium-based porous metal-organic framework and their high catalytic ability for the reverse water-gas shift reaction

作者：Xu, Haitao[1];Li, Yansong[1];Luo, Xikuo[1];Xu, Zhenliang[1];Ge, Jianping[2]

机构：[1]East China Univ Sci & Technol ECUST, Chem Engn Res Ctr, State Key Lab Chem Engn, Membrane Sci & Engn R&D Lab, 130 Meilong Rd, Shanghai 200237, Peoples R China;[2]East China Normal Univ, Sch Chem & Mol Engn, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China

年份：2017

卷号：53

期号：56

起止页码：7953

外文期刊名：CHEMICAL COMMUNICATIONS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000405186900020)】；

基金：We gratefully acknowledge the financial support from the National Natural Science Foundation of China (No. 21371058).

语种：英文

摘要：A highly active and selective Au@UIO-67 catalyst has been assembled. Gold nanoparticles (AuNPs) are monodispersed on the UIO-67 surface of a porous metal-organic framework, the micropores in UIO-67 as templates for adsorbing Au ions and enhancing interaction between AuNPs and UIO-67, favoring the formation of isolated and well-dispersed AuNPs. The catalyst exhibits high catalytic activity and CO selectivity for the reverse water-gas shift reaction in a fixed-bed flow reactor.