文献类型：期刊文献

英文题名：PolyHIPEs as novel media for conventional free radical chemistry

作者：Zhang, Shengmiao[1];Chen, Jianding[1];Perchyonok, Victoria T.[2]

机构：[1]E China Univ Sci & Technol, Sch Mat Sci & Engn, Key Lab Ultrafine Mat, Minist Educ, Shanghai 200237, Peoples R China;[2]Monash Univ, Sch Chem, Clayton, Vic 3080, Australia

年份：2008

卷号：5

期号：4

起止页码：304

外文期刊名：LETTERS IN ORGANIC CHEMISTRY

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000256193400013)】；

语种：英文

外文关键词：free radicals; polyHIPEs as reaction media; synthesis; green chemistry

摘要：The novel materials, polyHIPEs with incorporated tetrasubstituted ammonium cationic surfactant ( CTAB) have been applied to a broad range of radical precursors in various free radical transformations in organic and aqueous media. The advantage of this reagent/ solid phase surfactant combination lies in its affordability, miniscule toxicity, avoidance of highly toxic "tin based hydrogen donors" under green reaction conditions.