文献类型：期刊文献

英文题名：Advances of Ionic Liquids and Deep Eutectic Solvents in Green Processes of Biomass-Derived 5-Hydroxymethylfurfural

作者：Chen, Lifang[1];Xiong, Yuhang[1];Qin, Hao[2];Qi, Zhiwen[1]

机构：[1]East China Univ Sci & Technol, Sch Chem Engn, State Key Lab Chem Engn, Max Planck Partner Grp, 130 Meilong Rd, Shanghai 200237, Peoples R China;[2]Otto von Guericke Univ, Chair Proc Syst Engn, Univ Pl 2, D-39106 Magdeburg, Germany

年份：2022

卷号：15

期号：13

外文期刊名：CHEMSUSCHEM

收录：;EI(收录号：20220711643371);WOS:【SCI-EXPANDED(收录号:WOS:000753673800001)】；

基金：The financial support from the Natural Science Foundation of Shanghai (No. 19ZR1412500) and National Natural Science Foundation of China (No. 21776074) is greatly acknowledged.

语种：英文

外文关键词：5-hydroxymethylfurfural; biomass; deep eutectic solvents; ionic liquids; sustainable chemistry

摘要：5-Hydroxymethylfurfural (HMF) is identified as an important bio-based platform chemical to bridge petroleum-based and biomass-based resources. It can be obtained through dehydration of various carbohydrates as well as converted to value-added fuels and chemicals. As designer solvents, ionic liquids (ILs) and deep eutectic solvents (DESs) have been widely used in catalytic transformation of biomass derivatives to various chemicals. This Review summarizes recent progress in experimental and theoretical studies on dehydration of carbohydrates such as fructose, glucose, sucrose, cellobiose, chitosan, cellulose, inulin, and even raw biomass to generate HMF using ILs and DESs as catalysts/cocatalysts and/or solvents/cosolvents. It also gives an overview of IL and DES-involved catalytic transformation of HMF to downstream products via oxidation, reduction, esterification, decarboxylation, and so forth. Challenges and prospects of ILs and DESs are also proposed for further production of HMF and HMF derivatives from biomass in green and sustainable processes.