文献类型：期刊文献

中文题名：Interfacial growth of N,S-codoped mesoporous carbon onto biomass-derived carbon for superior potassium-ion storage

作者：Na Huang[1];Cheng Tang[2];Hao Jiang[3];Jie Sun[1];Aijun Du[2];Haijiao Zhang[1]

机构：[1]Institute of Nanochemistry and Nanobiology,School of Environmental and Chemical Engineering,Shanghai University,Shanghai 200444,China;[2]School of Chemistry and Physics and Centre for Materials Science,Queensland University of Technology,Brisbane,QLD 4001,Australia;[3]Shanghai Engineering Research Center of Hierarchical Nanomaterials,Frontiers Science Center for Materiobiology and Dynamic Chemistry,School of Materials Science and Engineering,East China University of Science and Technology,Shanghai 200237,China

年份：2024

卷号：17

期号：4

起止页码：2619

中文期刊名：Nano Research

外文期刊名：纳米研究（英文版）

收录：CSTPCD;;Scopus;CSCD:【CSCD2023_2024】；PubMed;

基金：supported by the Natural Science Foundation of Shanghai(No.23ZR1423800);the Shuguang Program from Shanghai Education Development Foundation and Shanghai Municipal Education Commission(No.18SG35);Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education);Nankai University.

语种：英文

中文关键词：mesoporous carbon(MC);biomass-derived carbon(BC);N;S co-doping;interfacial assembly;potassium-ion batteries(PIBs)

摘要：Carbonaceous materials have been recognized as one of the most promising anode materials for potassium-ion batteries(PIBs)due to their abundant raw materials,controllable structure,superior conductivity,and good chemical inertness.However,the large radius of K ions and the low potassium content of intercalation compounds result in the sluggish storage kinetics and low reversible capacity of carbon anodes.In this work,we present a unique heteroatom-doped carbon composite(denoted as NS-MC/SC)through a facile interfacial assembly route and simple heat-treatment process,where NS-MC is well grafted onto the biomass-derived spore carbon(SC).This unique structural design endows it with abundant mesoporous channels,expanded layer spacing,and highly doped N and S.With these merits,the NS-MC/SC anode in PIBs exhibits a high reversible capacity of 350.4 mAh·g^(-1) at 100 mA·g^(-1) after 300 cycles,and an outstanding cycling stability.Besides,in-situ Raman spectra further verify the high reversibility of K ions insertion/extraction.Importantly,theoretical simulations also reveal that the N,S dual-doping is an efficient approach for improving the potassium-ion storage performance of NS-MC/SC.