文献类型：期刊文献

英文题名：Copper-catalyzed imination of sulfoxides and sulfides

作者：Liu, Yuanyuan[1];Wang, Hanying[1];Yang, Xianjin[1,2]

机构：[1]East China Univ Sci & Technol, Key Lab Adv Mat & Inst Fine Chem, 130 Meilong Rd, Shanghai 200231, Peoples R China;[2]Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, 345 Lingling Rd, Shanghai 200032, Peoples R China

年份：2019

卷号：75

期号：33

起止页码：4697

外文期刊名：TETRAHEDRON

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000491426100033)，CCR-EXPANDED(收录号:WOS:000491426100033)】；

基金：This study was financially supported by the National Natural Science Foundation of China (21372077) and by State Key Laboratory of Efficient Utilization for Low Grade Phosphate Rock and Its Associated Resources (WFKF2017-04).

语种：英文

外文关键词：Copper-catalyzed; Sulfimidation; N-fluoro benzenesulfonamide; Imination; Metal-nitrene

摘要：Sulfoximines and sulfilimines have attracted considerable interest among organic chemists. The Cu(II)catalyzed imination of sulfoxides and sulfides using various N-fluoro benzenesulfonamides was investigated in this study. The scope of the reaction was demonstrated by using several substituted sulfides and sulfoxides. The flow strategy for the preparation of NH-sulfoximines was also examined. By trapping nitrene intermediates through triphenylphosphine, we found that the reaction was conducted through a metal-nitrene intermediate mechanism. (C) 2019 Elsevier Ltd. All rights Reserved.