详细信息
文献类型:期刊文献
中文题名:嘧啶类液晶化合物的合成及性能研究
英文题名:SYNTHESIS AND DETECTION OF LIQUID CRYSTALS OF THE PYRIMIDINE FAMILY
作者:龙玲[1];荣国斌[1]
机构:[1]华东理工大学化学系,上海200237
年份:1994
卷号:2
期号:3
起止页码:179
中文期刊名:液晶通讯
语种:中文
中文关键词:嘧啶类;液晶;化合物;性能;合成
外文关键词:Pyritnidine;Liquid Crystal;Synthesis
摘要:设计并合成了2—(4’—烷氧基苯基)—5—烷基—嘧啶,2—(2’—氟—4’烷氧基苯基)—5—烷基嘧啶,2—(3—’氟—4’—烷氧基苯基)—5—烷基—嘧啶和2—(4’—烷基联苯基)—嘧啶等四类液晶化合物并测定比较了它们的相态和介电常数,电阻率等物理常数。
Four series of 2-biphenyl and 2-phenyl as well as 2-laterally monofluoro-substi-ituted phenyl pyrimidines were synthesized and their mesomorphic and some physical properties were investigated. They are relatively lowmelting point with transition phases of I -SA-Sc and wide-range Sc phase. The compounds with extra fluorine especially in 2’-position (2) have lower melting points and phase - transition temperature, dielectric anisotropies become negative. It also can be seen that compound 3 have much greater smectic tendencies (particuiarly Sc) , but smectio phase was almost disappeared in 2. These compounds have been used as excellent hosts materials for TN and FLC systems.
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