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Synthesis and characterization of Cu2ZnSnSe4 nanocrystals prepared by one pot route  ( SCI-EXPANDED收录 EI收录)  

文献类型:期刊文献

英文题名:Synthesis and characterization of Cu2ZnSnSe4 nanocrystals prepared by one pot route

作者:Wang, Tingting[1];Chen, Qinmiao[2];Chen, Jin[1];Zhou, Fangfang[1];Jia, Zhen[1];Dou, Xiaoming[2,3];Zhuang, Songlin[1]

机构:[1]Shanghai Univ Sci & Technol, Shanghai Key Lab Modern Opt Syst, Engn Res Ctr Opt Instrument & Syst, Minist Educ, Shanghai 200093, Peoples R China;[2]E China Univ Sci & Technol, Dept Phys, Coll Sci, Shanghai 200237, Peoples R China;[3]Waseda Univ, Consolidated Res Inst Adv Sci & Med Care, Shinjuku Ku, Tokyo 1620041, Japan

年份:2014

卷号:49

期号:10

起止页码:808

外文期刊名:CRYSTAL RESEARCH AND TECHNOLOGY

收录:;EI(收录号:20144300129966);WOS:【SCI-EXPANDED(收录号:WOS:000342770600009)】;

基金:The project was supported by the Shanghai Committee of Science and Technology, China (No. 13JC1404300, No.10540500700), Foundation for The Youth Scholars of Shanghai Municipal Education Commission (No. ZZSLG13013), Teachers' Innovation Ability Construction of University of Shanghai for Science and Technology (No. GDCX-Y-1205), National Natural Science Foundation of China (No. 21205078), Research Fund for the Doctoral Program of Higher Education of China (No. 20123120110002), the Innovation Program of Shanghai Municipal Education Commission (No. 13YZ073), the Innovation Fund Project For Graduate Student of Shanghai (No.JWCXSL1301), and the Leading Academic Discipline Project of Shanghai Municipal Government (No.S30502).

语种:英文

外文关键词:Cu2ZnSnSe4; nanocrystals; one-pot route

摘要:Quaternary compound Cu2ZnSnSe4 (CZTSe) is one of the most promising absorber layer materials for thin film solar cells. In present work, the CZTSe nanocrystals were successfully synthesized via one pot route, and the influences of reaction temperature on the structural, compositional, morphological and optical properties of as-synthesized CZTSe nanocrystals were investigated in detail via X-ray powder diffraction (XRD), energy dispersive X-ray spectrometry (EDS), transmission electron microscopy (TEM) and UV-Vis spectrophotometry, respectively. The characterization results of as-synthesized nanocrystals, under optimal synthesis condition (250 degrees C, 1 h), indicated that the nanocrystals was monodispersed with polycrystalline, the size was in the range of 10-15 nm, and the band gap energy was around 1.44 eV which is very closed to the best band gap energy for the solar cell. All results suggested that the as-synthesized CZTSe nanocrystals were good light absorber layer material for thin film solar cell.

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