文献类型：期刊文献

中文题名：高炭树脂芳基乙炔聚合物炭化过程研究(Ⅱ)

英文题名：STUDIES ON THE PYROLYTIC PRODUCT OF HIGH CHAR POLYARYLACETYLENE(Ⅱ)

作者：丁学文[1];庄元其[2];王俊[2]

机构：[1]上海新天和树脂有限公司,上海201404;[2]华东理工大学材料学院,上海200237

年份：2004

卷号：19

期号：2

起止页码：5

中文期刊名：热固性树脂

外文期刊名：Thermosetting Resin

收录：CSTPCD;;CSCD:【CSCD_E2011_2012】；

基金：国家自然科学基金项目(编号29684001)

语种：中文

中文关键词：芳基乙炔聚合物;炭化;C/C复合材料;玻璃碳

外文关键词：polyarylacetylene;pyrolytic;C/C composites;glass carbon

摘要：通过XRD、FTIR和DTA等分析方法研究了芳基乙炔聚合物的炭化过程,结果表明:芳基乙炔聚合物的炭化过程可大致分为3个阶段;炭化温度在350～500℃时,聚合物结构变化较小;炭化温度在500～600℃时,聚合物主链结构被完全破坏,并转变为玻璃炭结构;炭化温度在600～900℃时,随炭化温度的增加,炭化物由玻璃炭结构逐渐向乱层石墨结构转变。
In this paper,the pyroytic process of polyarylacetylene was studied by X-ray diffraction FTIR and DTA methods.The results showed that the pyrolytic process of polyarylacetylene could be divided into three steps;at 350～500 ℃,the structure of polymer backbone hadn′t been destructed;at 500～600 ℃,the backbone of polymer had been destructed and changed to glass carbon structure;at 600～900 ℃,with the increase of pyrolytic temperature,the glass carbon structure had been changed to a kind of disorder graphite gradually.