文献类型：期刊文献

英文题名：Revisit the Hydrated Cation-π Interaction at the Interface: A New View of Dynamics and Statistics

作者：Yang, Yizhou[1];Liang, Shanshan[1];Wu, Hao[2,4];Shi, Guosheng[5];Fang, Haiping[1,2,3]

机构：[1]East China Univ Sci & Technol, Sch Phys, Shanghai 200237, Peoples R China;[2]Univ Chinese Acad Sci, Wenzhou Inst, Wenzhou 325001, Zhejiang, Peoples R China;[3]Chinese Acad Sci, China Shanghai Adv Res Inst, Shanghai 201204, Peoples R China;[4]Oujiang Lab Zhejiang Lab Regenerat Med Vis & Brai, Wenzhou 325001, Zhejiang, Peoples R China;[5]Shanghai Univ, Shanghai Appl Radiat Inst, State Key Lab Adv Special Steel, Shanghai 200444, Peoples R China

年份：2022

卷号：38

期号：8

起止页码：2401

外文期刊名：LANGMUIR

收录：;EI(收录号：20220911721065);WOS:【SCI-EXPANDED(收录号:WOS:000766043400001)】；

基金：This work was supported by the National Natural Science Foundation of China (12004110, 11974366), the Fundamental Research Funds for the Central Universities. We thank Ms. Jessica Ye for helpful editorial comments. We thank the APS Press (permission Figure 2a), American Chemical Society (permission Figure 2b, c), AAAS Press (permission Figure 2d), Springer Press (permission Figure 3a-d), RSC Publishing (permission Figure 3e), and IOP Publishing (permission Figure 4) for authorizing us the copyright(s).

语种：英文

外文关键词：Hydration - Phase interfaces - Molecular biology - Positive ions

摘要：Carbon-based matter, such as biomolecules and graphitic structures, often form a liquid-solid/soft matter interface in salt solution and continuously affect the surrounding cations through hydrated cation-pi interactions. In this Perspective, we revisit the effect of the hydrated cation-pi interactions at the interface using statistical physics, which reveals how hydrated cation-pi interactions affect every component dynamically and cause a time-dependent statistical effect at the liquid-solid/soft interface. We also highlight several pieces of experimental evidence from a statistical perspective and discuss the remarkable applications related to environmental protection, industrial manufacturing, and biological sciences.