文献类型：期刊文献

中文题名：固相热分解反应最可几机制的判断

英文题名：DECIDE ON PROBABLE REACTION MECHANISM OF THE THERMAL DECOMPOSITION OF SOLID

作者：高永煜[1];邹文樵[1];冯仰婕[1]

机构：[1]华东理工大学化学系

年份：1996

卷号：8

期号：2

起止页码：261

中文期刊名：化学研究与应用

外文期刊名：Chemical Research and Application

收录：CSTPCD;;CSCD:【CSCD2011_2012】；

语种：中文

中文关键词：热分解;反应机制;固相分解反应

外文关键词：Thermal decomposition,Kinetic equation,Mechanism of the reaction

摘要：固相热分解反应最可几机制的判断高永煜，邹文樵，冯仰婕（华东理工大学化学系上海２００２３７）关键词热分解，动力学方程，反应机制固相热分解反应机制的判断，是热分析动力学中令人感兴趣的领域。常用的方法是从含机制函数的非等温积分动力学方程出发，分别用Ｓｅｓｔ...
According to the reducible principle of non-isothermal kinetic curves￣[2],the reaction mechanism of thermal decomposition of solid was defined by the method of conbining integral kinetic equation with differential kinetic equation.The calculative results has been 5hown the sensitivity of the decided method is better than common linear method.Considering change of activation energy and frequency factor change with the temperature,decided mechanism comparably tallies with reality of the reaction.