文献类型：期刊文献

英文题名：Rh(III)-Catalyzed Hydroarylation of Alkyne MIDA Boronates via C-H Activation of Indole Derivatives

作者：Fei, Xiao[1,2,3,4];Li, Chunpu[3,4];Yu, Xinhong[1,2];Liu, Hong[3,4]

机构：[1]East China Univ Sci & Technol, Sch Pharm, State Key Lab Bioengn Reactors, Shanghai 200237, Peoples R China;[2]East China Univ Sci & Technol, Sch Pharm, Shanghai Key Lab New Drug Design, Shanghai 200237, Peoples R China;[3]Chinese Acad Sci, Shanghai Inst Mat Med, State Key Lab Drug Res, 555 Zu Chong Zhi Rd, Shanghai 201203, Peoples R China;[4]Chinese Acad Sci, Shanghai Inst Mat Med, Key Lab Receptor Res, 555 Zu Chong Zhi Rd, Shanghai 201203, Peoples R China

年份：2019

卷号：84

期号：11

起止页码：6840

外文期刊名：JOURNAL OF ORGANIC CHEMISTRY

收录：;EI(收录号：20192407036683);WOS:【SCI-EXPANDED(收录号:WOS:000471212000029)，CCR-EXPANDED(收录号:WOS:000471212000029)】；

基金：We gratefully acknowledge financial support from the National Natural Science Foundation of China (81620108027, 21632008, 91229204, 81220108025 and 81602975) the Major Project of Chinese National Programs for Fundamental Research and Development (2015CB910304), and National S&T Major Projects (2014ZX09507002-001, 2015ZX09103003).

语种：英文

外文关键词：Rhodium compounds - Activation analysis - Hydrocarbons - Catalysis

摘要：An efficient approach to trans-indolylvinylboronate derivatives has been developed using an Rh-catalyzed hydroarylation of alkyne N-methyliminodiacetic acid boronates via C-H activation. This protocol constitutes a straightforward route for the synthesis of B-containing aza-heterocycles in good yields with excellent functional group tolerance.