文献类型：期刊文献

英文题名：Study on the thermodynamics of solution containing alcohols I. Excess enthalpy model

作者：Zhang, LH; Shen, XY; Liu, GJ

机构：[1]E China Univ Sci & Technol, Dept Chem, Shanghai 200237, Peoples R China

年份：2002

卷号：60

期号：4

起止页码：617

外文期刊名：ACTA CHIMICA SINICA

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000175079300012)】；

语种：英文

外文关键词：solution containing alcohol; excess enthalpy; thermodynamic model; association

摘要：A thermodynamic model for mixing alcohols and hydrocarbons has been proposed. From this model, a simple equation of excess enthalpy which is composed of the physical and chemical contributions is obtained. The equation has good generality and can be extended to other solutions containing alcohols. It can be satisfactorily used not only to describe the relationship between the excess enthalpy and the composition, but to display the interaction between the components.