文献类型：期刊文献

英文题名：Prominent Electronic and Geometric Modifications of Palladium Nanoparticles by Polymer Stabilizers for Hydrogen Production under Ambient Conditions

作者：Jones, Simon[1];Qu, Jin[1,2];Tedsree, Karaked[3];Gong, Xue-Qing[2];Tsang, Shik Chi Edman[1]

机构：[1]Univ Oxford, Dept Chem, Oxford OX1 3QR, England;[2]E China Univ Sci & Technol, Res Inst Ind Catalysis, Shanghai 200237, Peoples R China;[3]Burapha Univ, Dept Chem, Fac Sci, Chon Buri 20131, Thailand

年份：2012

卷号：51

期号：45

起止页码：11275

外文期刊名：ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

收录：;EI(收录号：20124515640166);WOS:【SCI-EXPANDED(收录号:WOS:000310874400015)】；

语种：英文

外文关键词：hydrogen production; nanoparticles; palladium; pendant groups; polymers

摘要：A remarkable effect from the modification of electronic and geometric properties of Pd nanoparticles by the use of polymer pendant groups bound to the surface of palladium nanoparticles is reported. The degree of electron promotion to the Pd nanoparticles under ambient conditions was found to be dependent on the availability of the lone pair electrons of the pendant groups. Copyright ? 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.