文献类型：期刊文献

英文题名：The use of chiral BINAM NHC-Rh(III) complexes in enantioselective hydrosilylation of 3-oxo-3-arylpropionic acid methyl or ethyl esters

作者：Xu, Qin[1]; Gu, Xingxing[1]; Liu, Sijia[1]; Dou, Qinyu[1]; Shi, Min[1,2]

机构：[1]E China Univ Sci & Technol, Sch Chem & Mol Engn, Shanghai 200237, Peoples R China;[2]Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

年份：2007

卷号：72

期号：6

起止页码：2240

外文期刊名：JOURNAL OF ORGANIC CHEMISTRY

收录：;EI(收录号：20071210498911);WOS:【SCI-EXPANDED(收录号:WOS:000244773600047)，CCR-EXPANDED(收录号:WOS:000244773600047)】；

语种：英文

外文关键词：Chirality - Complexation - Enantioselectivity - Esters - Hydrosilylation - Organic acids

摘要：Axially chiral BINAM N-heterocyclic carbene (NHC)-Rh-(III) complexes were applied in the enantioselective hydrosilylation of 3-oxo-3-arylpropionic acid methyl or ethyl esters. The reduction products 3-hydroxy-3-arylpropionic acid methyl or ethyl esters could be obtained in good yields with good to excellent enantioselectivities under mild conditions.