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The studies on the mechanical and thermodynamic properties of surface fluorinated polypropylene/polypropylene blends  ( SCI-EXPANDED收录)  

文献类型:期刊文献

英文题名:The studies on the mechanical and thermodynamic properties of surface fluorinated polypropylene/polypropylene blends

作者:He, Haoming[4];Gao, Lei[1,2];Yang, Xianjin[1,2,3,4];Hu, Qingyang[1,2];Zhang, Yan[1,2];Chen, Guanlong[1,2];Wang, Jiangping[4];Yang, Sanke[4];Xie, Tian[4];Guo, Weihong[1,2]

机构:[1]E China Univ Sci & Technol, Adv Mat Lab, Shanghai 200237, Peoples R China;[2]E China Univ Sci & Technol, Inst Fine Chem, Shanghai 200237, Peoples R China;[3]Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, Shanghai 200032, Peoples R China;[4]Wengfu Grp Co Ltd, Shanghai 200032, Guizhou, Peoples R China

年份:2013

卷号:151

起止页码:32

外文期刊名:JOURNAL OF FLUORINE CHEMISTRY

收录:;WOS:【SCI-EXPANDED(收录号:WOS:000320352000006)】;

基金:This work was supported by Guizhou Wengfu Group Company and Chinese Postdoctor Foundation.

语种:英文

外文关键词:Direct fluorination; Surface fluorinated polypropylene; Blend; Mechanical property; Thermodynamic property

摘要:The surface fluorinated polypropylene and PP (SFPP/PP) blend was obtained by direct fluorination of polypropylene particle with 3% F-2/N-2 gas and subsequent blending with polypropylene particle. The analyses indicated that the mechanical and thermodynamic properties of SFPP/PP blends such as tensile strength, impact strength, flexural strength, and cooling crystallization characteristics varied with the ratio of SFPP/PP. With the increase of SFPP in the blend, the tensile strength was decreased, while the impact strength and flexural strength might be improved. Meanwhile, fluorination resulted in the rise of melting point of PP. and in the DSC plot of SFPP/PP, annealing made the melting single peak split into double peak, which demonstrated that SFPP and PP were compatible but instable. (c) 2013 Elsevier B.V. All rights reserved.

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