文献类型：期刊文献

英文题名：Effects of nonionic surfactant and salts on the interactions between oppositely charged star-shaped copolymer and ionic surfactant in aqueous solutions

作者：Guo, Yi[1];Shen, Jingwen[1];Li, Meng[1];Shang, Yazhuo[1];Liu, Honglai[1]

机构：[1]East China Univ Sci & Technol, Sch Chem & Mol Engn, Key Lab Adv Mat, Shanghai 200237, Peoples R China

年份：2018

卷号：266

起止页码：789

外文期刊名：JOURNAL OF MOLECULAR LIQUIDS

收录：;EI(收录号：20182805530995);WOS:【SCI-EXPANDED(收录号:WOS:000442976500088)】；

基金：This work is supported by the National Natural Science Foundation of China (Project No. 21476072) and the Fundamental Research Funds for the Central Universities.

语种：英文

外文关键词：Star-shaped copolymer; Surfactant; Interaction; Thermo-sensitive; Salt

摘要：The interaction between star-shaped copolymer poly(2-(dimethylamino)ethyl methacrylate-b-2-(2-methoxyethoxy)ethyl methacrylate) (CDPDPM) and anionic surfactant sodium dodecyl sulfate (SDS) in aqueous solutions are investigated by using fluorescence and dynamic light scattering (DLS) techniques. The effects of nonionic surfactant dodecyl beta-D-maltopyranoside (C(12)G(2)) and salts including inorganic salt ammonium bromide (NH4Br) and organic salt tetra-n-butylammonium bromide (Bu4NBr) on the interaction between CDPDPM and SOS have been explored systematically. The results have suggested that SDS molecules can bind on CDPDPM by electrostatic interaction between the positively charged CDPDPM and negatively charged SDS and thus weaken the binding ability of CDPDPM to water molecules. CDPDPM exhibits temperature-responsive aggregation behavior in aqueous solution gradually with the increase of SDS concentration and the lower critical solution temperature (LCST) decreases correspondingly. The introduction of nonionic surfactant C(12)G(2) changes the interaction between CDPDPM and SDS significantly by participate the formation of complexes and the stability of the CDPDPM/SDS complexes declines leading to the chance of forming larger complexes is deprived at higher temperature. The addition of NH4Br to the CDPDPM/SDS system can retard the binding of SDS on the polymer chains because of electrostatic shielding. Correspondingly, LCST is higher and the formed aggregates are smaller. For CDPDPM/Bu4NBr/SDS system, the phenomenon is similar to that of the CDPDPM/C(12)G(2)/SDS system. This should be attributed to the nature of Bu4N+, possesses not only positive charges but also certain hydrophobicity, and thus Bu4N+ has the ability to participate and facilitate the formation of SOS micelles. Obviously, the LCST of the mixed system can be tailored by adjusting the system composition on purpose. (C) 2018 Elsevier B.V. All rights reserved.