文献类型：期刊文献

英文题名：Preparation and Surfactant-Assisted Morphology-Controllable Growth of ZnIn₂S₄

作者：Wei Qing-Lian[1];Mu Shuai[1];Yan Ya[1];Lue Ying[1];Kang Shi-Zhao[2];Mu Jin[1]

机构：[1]E China Univ Sci & Technol, Dept Chem, Shanghai 200237, Peoples R China;[2]Shanghai Inst Technol, Dept Chem Engn, Shanghai 200235, Peoples R China

年份：2010

卷号：26

期号：2

起止页码：269

外文期刊名：CHINESE JOURNAL OF INORGANIC CHEMISTRY

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000274766300015)】；

语种：英文

外文关键词：ZnIn2S4; wet chemistry synthesis; mercaptoacetic acid; surfactant; morphology-controllable growth

摘要：The ZnIn2S4 ternary compound with a hexagonal structure was prepared by the wet chemistry synthesis route using mercaptoacetic acid as capping agent and water as solvent. The composition, structure, morphology and optical properties of the product were characterized by means of energy dispersive X-ray spectrometry (EDS), X-ray diffraction (XRD), transmission electron microscope (TEM), scanning electron microscopy (SEM) and ultraviolet-visible spectra (UV-Vis). The ZnIn2S4 obtained shows the laminar shape. In addition, the morphology-controllable growth of ZnIn2S4 was successfully achieved at. the solid/liquid interface using ZnIn2S4 nanoparticles precursor as initial materials with the aid of the surfactants as orienting agents. The rod-, rod-cluster- and tubule-cluster-shaped ZnIn2S4 were prepared. The growth mechanism for the shape controlling of ZnIn2S4 was discussed.