文献类型：期刊文献

英文题名：Bis(NHC)-Palladium(II) Complex-Catalyzed Dioxygenation of Alkenes

作者：Wang, Wenfeng[1,2];Wang, Feijun[1,2];Shi, Min[1,2,3]

机构：[1]E China Univ Sci & Technol, Sch Chem & Mol Engn, Adv Mat Lab, Shanghai 200237, Peoples R China;[2]E China Univ Sci & Technol, Sch Chem & Mol Engn, Inst Fine Chem, Shanghai 200237, Peoples R China;[3]Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

年份：2010

卷号：29

期号：4

起止页码：928

外文期刊名：ORGANOMETALLICS

收录：;EI(收录号：20100812724652);WOS:【SCI-EXPANDED(收录号:WOS:000274530400027)】；

基金：We thank the Shanghai Municipal Committee of Science and Technology (06XD14005, 08dj1400100-2), National Basic Research Program of China (973-2009CB825300), and the National Natural Science Foundation of China (20472096, 20872162, 20672127, 20821002, and 20732008) for financial support.

语种：英文

外文关键词：Catalyst activity - Hydrocarbons

摘要：Bis(NHC)-Pd(II) complexes derived from 1,1'-binaphthyl-2,2'-diamine (BINAM) were successfully first used to catalyze the dioxygenation of alkenes under mild conditions tolerant of air and moisture. Cationic NHC-Pd2+ diaquo complex le showed the highest catalytic activity to give 1,2-dioxygenation products with good syn-diastercoselectivity for 1,2-disubstituted alkenes.