文献类型：期刊文献

英文题名：Homopolymerization of methyl methacrylate by Ni(II)(salophen) Complex

作者：Li, Dongya[1]; Zhang, Danfeng[1]

机构：[1] Shanghai Key Laboratory of Advanced Polymeric Materials, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai, 200237, China

年份：2018

卷号：397

期号：1

外文期刊名：IOP Conference Series: Materials Science and Engineering

收录：EI(收录号：20183805838434)

语种：英文

外文关键词：Acrylic monomers - Esters - Molecular weight distribution - Nickel compounds

摘要：A new Ni(II)(salophen) complex (C1)was used to polymerize MMA in the presence of methyl aluminoxane (MAO). It shows better activity in MMA polymerization up to 105 (g?mol-1Ni?h-1), higher molecular weight and narrower molecular weight distribution. The products are syndiotactic PMMA with better mechanical properties. ? Published under licence by IOP Publishing Ltd.