文献类型：期刊文献

英文题名：Capture of CO₂ from flue gas by vacuum pressure swing adsorption using activated carbon beads

作者：Shen, Chunzhi[1,2];Yu, Jianguo[1];Li, Ping[1];Grande, Carlos A.[2];Rodrigues, Alirio E.[2]

机构：[1]E China Univ Sci & Technol, State Key Lab Chem Engn, Coll Chem Engn, Shanghai 200237, Peoples R China;[2]Univ Porto, Lab Separat & React Engn LSRE, Associate Lab LSRE LCM, Dept Chem Engn,Fac Engn, P-4200465 Oporto, Portugal

年份：2011

卷号：17

期号：1

起止页码：179

外文期刊名：ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000286665400019)】；

基金：The authors are grateful for the financial support of China 863 program (Grant No. 2008AA062302), Shanghai international cooperation project (Grant No. 08160704000), Shanghai Pujiang Talent program (Grant No. 08PJ14034) and the fellowship from China Scholarship Council (CSC) for the stay of C.S. at LSRE. The authors also acknowledge Professor Ling Licheng to provide the activated carbon beads.

语种：英文

外文关键词：Vacuum pressure swing adsorption; Activated carbon beads; CO2 adsorption; Simulation; Breakthrough curve

摘要：Vacuum pressure swing adsorption (VPSA) for CO2 capture has attracted much research effort with the development of the novel CO2 adsorbent materials. In this work, a new adsorbent, that is, pitch-based activated carbon bead (AC bead), was used to capture CO2 by VPSA process from flue gas. Adsorption equilibrium and kinetics data had been reported in a previous work. Fixed-bed breakthrough experiments were carried out in order to evaluate the effect of feed flowrate, composition as well as the operating pressure and temperature in the adsorption process. A four-step Skarstrom-type cycle, including co-current pressurization with feed stream, feed, counter-current blowdown, and counter-current purge with N-2 was employed for CO2 capture to evaluate the performance of AC beads for CO2 capture with the feed compositions from 15-50% CO2 balanced with N-2. Various operating conditions such as total feed flowrate, feed composition, feed pressure, temperature and vacuum pressure were studied experimentally. The simulation of the VPSA unit taking into account mass balance, Ergun relation for pressure drop and energy balance was performed in the gPROMS using a bi-LDF approximation for mass transfer and Virial equation for equilibrium. The simulation and experimental results were in good agreement. Furthermore, two-stage VPSA process was adopted and high CO2 purity and recovery were obtained for post-combustion CO2 capture using AC beads.