文献类型：期刊文献

中文题名：间苯氧基苯甲醛及其衍生物的GC/MS研究

英文题名：Analysis of Meta phenoxybenzaldehyde and Their Derivations by GC/MS

作者：诸培奋[1];何振华[1];沙惠鑫[1];苏克曼[1]

机构：[1]华东化工学院分析测试中心,上海200237

年份：1993

卷号：14

期号：4

起止页码：30

中文期刊名：质谱学报

外文期刊名：Journal of Chinese Mass Spectrometry Society

收录：CSTPCD;;Scopus;CSCD:【CSCD2011_2012】；

语种：中文

中文关键词：间苯氧基;苯甲醛;衍生物;GC/MS

外文关键词：meta phenoxybenzaldehyde, derivations, GC/MS

摘要：本文介绍间苯氧基苯甲醛产品及其原料的GC/MS分析。该系列化合物和它的衍生物的质谱均出现较强的分子离子峰,文中列出了检测到的十六种化合物,并根据基峰的变化确定氯原子取代的位置是在苯环上或是取代在甲基上。此外,还对间苯氧基苯甲醛生产过程中存在的副反应进行了推导,给出三类副反应式,并在GC/MS实验结果中得到证实。
The product of meta phenoxybenzaldehyde and their raw stuff are analysed by gas chromatography/mass spectrometry. The mass spectra of series of compounds and their derivations all showed stronger molecular ions. Sixteen kinds of compounds measured were listed in the paper. According to change of base peak, the prosthetic position of chlorie can be affirmed that is on the benzene or on the methyl. And then the side reaction in the production of meta phenoxybenzaldehyde are derived. Three kind of side reactions are given and it is confirmed from analysis of GC/MS experimental results.