文献类型：期刊文献

中文题名：超级电容器用PbO2电极的电沉积工艺

英文题名：Electrodeposition Technique of PbO_2 Electrode Applied in Supercapacitor

作者：张波[1,1,2];钟菊花[1];程振民[2]

机构：[1]华东理工大学物理系,上海200237;[2]华东理工大学化学工程联合国家重点实验室,上海200237

年份：2011

卷号：37

期号：2

起止页码：193

中文期刊名：华东理工大学学报（自然科学版）

外文期刊名：Journal of East China University of Science and Technology

收录：CSTPCD;;Scopus;北大核心:【北大核心2008】；CSCD:【CSCD2011_2012】；

语种：中文

中文关键词：电化学电容器;电沉积PbO2;活性炭;充放电性能

外文关键词：electrochemical capacitor; electro-deposited PbO_2; active carbon; charge-discharge performance

摘要：以钛板为基底,采用电沉积方法制备了Ti-PbO2电极,与活性炭(AC)组成超级电容器。研究了铅盐种类对电沉积PbO2电极放电性能的影响,发现用Pb(CH3COO)2做溶质的氢氧化钠溶液制备的PbO2电极容量最大。利用不同浓度的氢氧化钠溶液配置饱和醋酸铅电解液,制备PbO2电极进行了放电测试,研究了氢氧化钠浓度对电沉积PbO2放电性能的影响。采用最优电沉积PbO2作正极,活性炭、涂膏铅电极作负极,分别组装成超级电容器和铅酸电池进行大电流充放电,结果表明,超级电容器性能远高于铅酸电池。
Ti/PbO_2 electrode was prepared by means of electrochemical deposition.PbO_2-AC super-capacitor was assembled by PbO_2 and active carbon（AC）.Effects of different lead salts on the discharge capacity of electrodeposited PbO_2 electrode were studied.The PbO_2 electrode prepared using sodium hydroxide solution containing Pb（CH_3COO）_2 had the largest capacity.Different samples of PbO_2 electrode were prepared in sodium hydroxide solutions with different concentration containing saturated lead acetate,and then were assembled with AC to conduct discharge test of PbO_2-AC super-capacitor.Two PbO_2 electrodes prepared by the optimized method were employed as anode,while AC and pasted lead electrode were employed as cathode,constructing the PbO_2-AC super-capacitor and lead acid battery respectively.Then,the charge-discharge tests with large current were conducted,and results indicated that the performance of super-capacitor was far above the performance of lead acid battery.