文献类型：期刊文献

英文题名：Catalytic effect of praseodymium oxide additive on the microstructure and electrical property of graphite anode

作者：Wang, Rongyan[1];Lu, Guimin[1];Qiao, Wenming[2];Sun, Ze[1];Zhuang, Haizheng[1];Yu, Jianguo[1,2]

机构：[1]E China Univ Sci & Technol, Natl Engn Res Ctr Integrated Utilizat Salt Lake R, Shanghai 200237, Peoples R China;[2]E China Univ Sci & Technol, State Key Lab Chem Engn, Shanghai 200237, Peoples R China

年份：2015

卷号：95

起止页码：940

外文期刊名：CARBON

收录：;EI(收录号：20154101377684);WOS:【SCI-EXPANDED(收录号:WOS:000363312900111)】；

基金：This work was supported by National Science Foundation of China (U1407202).

语种：英文

外文关键词：Catalytic graphitization; Praseodymium oxide; Rare-earth element; Carbon material

摘要：Based on the revealed interactions (dissociation energy) between several typical metals (transition and rare-earth elements) and carbon atoms through the DFT quantum mechanics method, Pr can be predicted to possibly be a new potential catalyst. Indeed, Praseodymium oxide (Pr6O11) was insightfully found to catalyze the graphitization more efficiently than the other selected additives. The effects of Pr6O11 catalyst on the microstructure of the graphite anode were investigated by XRD, Raman spectroscopy, SEM, and TEM. The results indicate that Pr6O11 addition remarkably improves the formation of crystallites, thereby largely enhancing the electrical property of graphite anode. The graphite anode with a low electrical resistivity of 5.0 mu Omega m was successfully available by adding 3 wt. % Pr6O11 at 2800 degrees C. Finally, the catalytic graphitization mechanism of rare-earth element was proposed based on the experimental results. (C) 2015 Elsevier Ltd. All rights reserved.