文献类型：期刊文献

英文题名：Relation of silver electrode solderability to intermetallic compound growth rate

作者：Zhang, Jiefeng[1];Li, Guoqing[1];Yuan, Xiao[1];Zhao, Hua[1];Yang, Yunxia[1];Li, Hongbo[1];Tong, Hua[1]

机构：[1]East China Univ Sci & Technol, Sch Mat Sci & Engn, Shanghai 200237, Peoples R China

年份：2019

卷号：30

期号：8

起止页码：7209

外文期刊名：JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS

收录：;EI(收录号：20191606792063);WOS:【SCI-EXPANDED(收录号:WOS:000467637200002)】；

基金：This study was partly supported by the Shanghai Science and Technology Committee Project [Number 17DZ1201102]. We also acknowledge the support from the National Natural Science Foundation of China [Grant Number 51202272] and Shanghai Municipal Science and Technology Commission [Grant Number 16DZ2260600].

语种：英文

外文关键词：Binary alloys - Electrodes - Glass - Glass transition - Intermetallics - Silicon compounds - Tin alloys

摘要：The reliability of crystalline silicon (c-Si) photovoltaic modules has a strong dependence on the silver (Ag) electrode solderability. To achieve desirable soldering, the reaction that occurs between Ag electrode and solder (Sn/Pb alloy) need to be comprehensively understood and elaborately controlled. In this article, the correlation of Ag electrode soldering states with intermetallic compound (Ag3Sn) growth was discussed. It was found that the reaction dynamics of Ag electrode and solder was closely associated with the glass frit in Ag paste. Here taken for exemplification were three kinds of V-B-Si oxide glass frit, which led to diverse soldering states for the Ag electrode, e.g. inveracious soldering, appropriate soldering and over-soldering, owing to their different affection on the Ag3Sn growth rate. The effect of glass frit on the Ag3Sn growth was addressed from the aspects of glass phase transition temperature, distribution of glass phase in electrode, and reaction between glass and solder. In addition, it was also demonstrated that the amount of glass frit added in Ag paste might impose significant affection on the solderability of the sintered electrode.