文献类型：期刊文献

中文题名：TBPB-TBPO引发不饱和聚酯树脂固化的动力学

英文题名：Kinetic of Unsaturated Polyester Resin with TBPB-TBPO

作者：倪秋如[1];倪礼忠[1];夏宏伟[2];冯伟祖[2];黄增琦[2];周权[1]

机构：[1]华东理工大学材料科学与工程学院,特种功能高分子材料及相关技术教育部重点实验室,上海200237;[2]无锡新宏泰电器科技股份有限公司,江苏无锡214174

年份：2014

卷号：27

期号：3

起止页码：348

中文期刊名：功能高分子学报

外文期刊名：Journal of Functional Polymers

收录：CSTPCD;;北大核心:【北大核心2011】；CSCD:【CSCD2013_2014】；

语种：中文

中文关键词：TBPO;TBPB;不饱和聚酯树脂;固化反应;双峰

外文关键词：TBPO; TBPB; unsaturated polyester resin; curing reaction; two peaks

摘要：采用差示扫描量热法(DSC)对不饱和聚酯(UP)树脂复配引发体系进行固化动力学研究,复配引发剂为过氧化苯甲酸叔丁酯(TBPB)-过氧化辛酸酯(TBPO)。采用高斯(Gaussian)分峰法对DSC曲线上的固化放热峰进行双峰拟合,并通过Ozawa方程对拟合结果进行固化动力学参数分析。研究表明:Gaussian双峰拟合后得到的结果与实验数据非常吻合,固化动力学参数更贴近实际固化过程。
The curing behavior of unsaturated polyester resin with complex initiation system TBPB-TBPO was studied by DSC.Gaussian model was used to fit two peaks,and curing kinetic analysis was made by Ozawa method.Results showed that fitting peaks were quite fit to experiment data and kinetic parameters calculated by fitting peaks divided by Gaussian model were close to the experiment data.