文献类型：期刊文献

英文题名：Ethylene trimerization with a half-sandwich titanium complex bearing a pendant thienyl group

作者：Huang, JL; Wu, TZ; Qian, YL

机构：[1]E China Univ Sci & Technol, Organomet Chem Lab, Shanghai 200237, Peoples R China

年份：2003

期号：22

起止页码：2816

外文期刊名：CHEMICAL COMMUNICATIONS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000186275100027)，CCR-EXPANDED(收录号:WOS:000186275100027)】；

语种：英文

摘要：A half-sandwich titanium complex with a pendant thienyl group, activated by methylalumoxane (MAO), can trimerize ethylene to 1-hexene with considerable activity and high selectivity; the coodination of the sulfur atom to the titanium center is proposed to be responsible for the selective trimerization of ethylene.