详细信息
文献类型:期刊文献
中文题名:苯氧化制顺丁烯二酸酐的反应动力学
英文题名:Study of Kinetics of the Catalytic Oxidation of Benzene to Maleic Anhydride
作者:朱海东[1];张濂[1];沈瀛坪[1]
机构:[1]华东化工学院联合化学反应工程研究所
年份:1989
卷号:15
期号:3
起止页码:293
中文期刊名:华东化工学院学报
收录:国家哲学社会科学学术期刊数据库;Scopus;CSCD:【CSCD2011_2012】;
语种:中文
中文关键词:顺丁烯二酸酐;苯;固定床反应器
外文关键词:kinetics; fixed bed reactor; benzene; maleic anhydride; catalytic reaction
摘要:用V_2O_5为活性组分的SD固体催化剂,在等温积分反应器中研究了文题。实验在工业生产操作条件下进行,用氧化还原动力学模型进行参数估值,给出了苯氧化反应动力学参数,该参数可用于反应器模拟计算。
The reaction kinetics of the oxidation of benzene to maleic anhydride over vanadium oxide catalysts has been studied in an isothermal integral reactor in the temperature range from 360 to 400℃. The rate data were correlated by the expressions based upon the steady state oxidation-reduction model. The parameters of kinetics has been obtained and can be used for both research and design of industrial reactors.
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