文献类型：期刊文献

英文题名：Copper-catalyzedortho-C(sp2)-H amination of benzamides and picolinamides with alkylamines using oxygen as a green oxidant

作者：Li, Qiong[1];Huang, Jie[1];Chen, Gong[2,3];Wang, Shui-Bo[1]

机构：[1]East China Univ Sci & Technol, Sch Chem & Mol Engn, Shanghai 200237, Peoples R China;[2]Nankai Univ, Coll Chem, State Key Lab, Tianjin 300071, Peoples R China;[3]Nankai Univ, Coll Chem, Inst Elementoorgan Chem, Tianjin 300071, Peoples R China

年份：2020

卷号：18

期号：25

起止页码：4802

外文期刊名：ORGANIC & BIOMOLECULAR CHEMISTRY

收录：;EI(收录号：20202808920052);WOS:【SCI-EXPANDED(收录号:WOS:000544474600015)，CCR-EXPANDED(收录号:WOS:000544474600015)】；

基金：This work was supported by the Fundamental Research Funds for the Central Universities (222201814019).

语种：英文

外文关键词：Copper - Catalysis - Amination - Oxidants - Amines

摘要：A versatile Cu-catalyzed directortho-C(sp(2))-H amination of benzamides and picolinamides with alkylamines has been achieved. This method employs cheap and eco-friendly copper as a catalyst and oxygen as an oxidant, and also has the advantages of straightforward steps and excellent functional group compatibility. Further application of our approach was demonstrated by the synthesis ofTCMDC-125116,SPHINX, andSRPIN340.