文献类型：期刊文献

英文题名：Recent advances in transition metal-catalyzed reactions of carbamoyl chlorides

作者：Shrestha, Mohini[1,2];Wu, Xianqing[1,2];Huang, Wenyi[1,2];Qu, Jingping[1,2];Chen, Yifeng[1,2]

机构：[1]East China Univ Sci & Technol, Sch Chem & Mol Engn, Frontiers Sci Ctr Mat & Dynam Chem, Key Lab Adv Mat,Feringa Nobel Prize Scientist Joi, 130 Meilong Rd, Shanghai 200237, Peoples R China;[2]East China Univ Sci & Technol, Sch Chem & Mol Engn, Frontiers Sci Ctr Mat & Dynam Chem, Feringa Nobel Prize Scientist Joint Res Ctr,Joint, 130 Meilong Rd, Shanghai 200237, Peoples R China

年份：2021

卷号：8

期号：14

起止页码：4024

外文期刊名：ORGANIC CHEMISTRY FRONTIERS

收录：;EI(收录号：20212910653445);WOS:【SCI-EXPANDED(收录号:WOS:000649431000001)】；

基金：This work was supported by NSFC/China (21702060), the Shanghai Rising-Star Program, the Shanghai Municipal Science and Technology Major Project (Grant No.2018SHZDZX03), the Program of Introducing Talents of Discipline to Universities (B16017), and the Fundamental Research Funds for the Central Universities.

语种：英文

外文关键词：Transition metals - Chlorine compounds - Catalysis - Fluorine compounds

摘要：The development of carbamoyl chlorides as synthons for various amide-containing molecules and heterocycles has been summarized and discussed in this review article. Carbamoyl chlorides can participate in a diverse range of transition metal-catalyzed transformations including radical initiated reactions and cross-coupling and annulation reaction modes as well as C-H functionalization to access amide-functionalized organic frameworks having extensive applications in pharmaceutical and natural product synthesis. This review mainly highlights the advancements of carbamoyl chlorides as a powerful synthetic tool in transition-metal catalyzed reactions over the last two decades. In addition, transition-metal catalyzed reactions of their corresponding structural analogs, carbamoyl fluorides and cyanides, with respect to their chemical behavior are also briefly reviewed.