文献类型：期刊文献

中文题名：介孔分子筛的功能化制备及催化性能研究进展

英文题名：Preparation and catalytic activities of functionalized mesoporous molecular sieves

作者：詹望成[1];卢冠忠[1];王艳芹[1]

机构：[1]结构可控先进功能材料及其制备教育部重点实验室华东理工大学工业催化研究所,上海200237

年份：2006

卷号：25

期号：1

起止页码：1

中文期刊名：化工进展

外文期刊名：Chemical Industry and Engineering Progress

收录：CSTPCD;;Scopus;北大核心:【北大核心2004】；CSCD:【CSCD2011_2012】；

基金：上海市科委重大基础研究项目(No.03DJ14006)

语种：中文

中文关键词：介孔分子筛;功能化;制备;杂原子取代;嫁接;负载

外文关键词：mesoporous molecular sieve; functionalization; preparation; heteroatomic substitution;graft; support

摘要：介绍了介孔分子筛经杂原子取代,引入酸功能、氧化还原功能;经有机-无机嫁接(杂合),引入聚合催化功能、酸催化功能、手性催化功能;经修饰的介孔分子筛,用作固定化酶催化剂的载体;作为催化剂的载体,用于负载过渡金属及其氧化物和制备负载化的固体酸催化剂。综述了介孔分子筛经功能化制备及催化性能的研究进展。
The preparation of functionalized mesoporous molecular sieves were introduced, which are including the formation of the acid active sites, redox active sites and used the support for immsobilizing enzyme catalysts by heteroatomic substitution; the formation of polymerization active sites, acid active sites or chiral catalysis sites by the organic- inorganic graft （or hybridization）; as the carriers, the transition metals, transition metal oxides and acid catalysts are supported. The progresses on the preparation and catalytic activities of the functionalized mesoporous molecular sieves are reviewed.