文献类型：期刊文献

中文题名：甲醇燃料车尾气净化催化剂的研究（Ⅰ）──单组分催化剂对甲醇的深度氧化

英文题名：Method for Treating the Exhaust Gases from a Methanol Fueled Internal Combustion Engine:(Ⅰ)Deep Oxidation of CH_3OH over Basic Metal Oxides and Precious Metal Catalysts

作者：王金安[1];汪仁[1]

机构：[1]华东理工大学工业催化研究所

年份：1994

卷号：15

期号：2

起止页码：45

中文期刊名：环境科学

外文期刊名：Environmental Science

收录：CSTPCD;;Scopus;北大核心:【北大核心1992】；CSSCI:【CSSCI1998】；CSCD:【CSCD2011_2012】；PubMed;

语种：中文

中文关键词：催化剂;甲醇;深度氧化;汽车排气

外文关键词：methanol, formaldehyde,deepoxidation,catalyst.

摘要：利用色谱－微反联用技术对甲醇深度氧化进行了研究。结果表明：甲醇在所有催化剂上氧化时均产生副产物甲醛及甲酸甲酯；非贵金属氧化物催化剂以Ｃｕ－Ｏ／ｒ－Ａｌ２Ｏ３的活性最优，其最佳负载量为１０％－２０％，不同的制备方法中以均匀沉淀法制备的催化剂最好；贵金属催化剂中Ａｇ／ｒ－Ａｌ２Ｏ３的活性较好，其甲醇氧化的Ｔ５０，Ｔ９５分别只有１３５℃和１９０℃，而且伴生的甲醛及甲酸甲酯浓度也较低。不同催化剂的活性与其氧化物的生成焓之间存在“火山”型曲线关系。
It was found that the deep oxidation of CH3OH overall the different catalysts studied produced bothHCHO and HCOOCH3.Among the basic medal oxidecatalysts,CuO/r-Al2O3 exhibited the best activitywith an optimum loading of about 10%-20%. Thecatalyst CuO/r-Al2O3 prepared with the method ofhomogeneous coprecipitution had a better activitythan others. Among the precious metal catalystsstudied,Ag/r-Al2O3 was the best one and had T5o 135℃ and T95=190℃ for the oxidation ofCH3OH. The different catalysts bed a 'volcano'type of curve relationship between their activitiesand △H.