文献类型：期刊文献

中文题名：HAP自组装球的简易合成及其光催化增效作用

英文题名：Facile Synthesis of Assembly HAP Nanoribbon Spheres and the Synergized Action of Its Photocatalytic Properties

作者：杨小红[1];刘畅[2];刘金库[2];朱子春[1]

机构：[1]池州学院化学系,安徽池州247000;[2]华东理工大学化学系,上海200237

年份：2011

卷号：27

期号：12

起止页码：2939

中文期刊名：物理化学学报

外文期刊名：Acta Physico-Chimica Sinica

收录：CSTPCD;;Scopus;WOS:【SCI-EXPANDED(收录号:WOS:000298618200032)】；北大核心:【北大核心2008】；CSCD:【CSCD2011_2012】；

基金：The project was supported by the National Natural Science Foundation of China (21071024), Science and Research Program of Anhui Province, China (10140702017), Key Project of Education Office of Anhui Provincem, China (KJ2010A244) and State Key Laboratory of Pollution Control, Resource Reuse Foundation, China (PCRRF09005).

语种：中文

中文关键词：羟基磷灰石;氧化锌;纳米组装球;光催化;增效作用

外文关键词：HAP; ZnO; Assembly sphere; Photocatalysis; Synergized action

摘要：选择生物协同模板,通过简单的控制组装工艺,制备出结构均一有序的羟基磷灰石(HAP)纳米组装球.该纳米组装球整体尺寸约5-6μm,球体中心部分尺寸约为2.5-3μm.通过X射线粉末衍射(XRD)、透射电子显微镜(TEM)、扫描电子显微镜(SEM)、傅里叶变换红外(FT-IR)光谱、比表面积(BET)测试等手段对产物形貌、结构和比表面积进行了表征.产物作为催化剂载体,对氧化锌催化降解罗丹明B(RhB)的催化效率提高了125%,催化剂回收率提高了23.1%,有效降低了催化剂的用量,在有机物降解领域具有潜在的应用价值.同时还对产物的控制生成过程和催化增效机理做了初步探讨.
Hydroxyapatite （HAP） nanoribbon spheres with well-defined nanoscale structures and regular morphology were successfully synthesized using a bioactive cooperate template. The spheres are about 5-6 pm in diameter and they form from nanoribbons of 2.5 to 3 pm in length. The morphologies, structures, and surface areas of the products were studied by X-ray diffraction （XRD）, transmission electron microscopy （TEM）, scanning electron microscopy （SEM）, Fourier transform infrared （FT-IR） spectroscopy and Brunauer-Emmett-Teller （BET） analysis. In addition, the products were used as carried materials for the synthesis of the HAP/ZnO composite catalyst. The degradation rate of rhodamine B （RhB） increased by 125% and the recovery increased by 23.1% when using the composite as a catalyst compared with the ZnO nanoparticles. Possible mechanisms for the formation of the HAP assembly microspheres and their synergistic action are also discussed.