文献类型：期刊文献

英文题名：Copper-Catalyzed Intermolecular Trifluoromethylazidation and Trifluoromethylthiocyanation of Allenes: Efficient Access to CF3-Containing Ally! Azides and Thiocyanates

作者：Zhu, Na[1];Wang, Fei[2];Chen, Pinhong[2];Ye, Jinxing[1];Liu, Guosheng[2]

机构：[1]E China Univ Sci & Technol, Sch Pharm, Minist Educ, Engn Res Ctr Pharmaceut Proc Chem, Shanghai 200237, Peoples R China;[2]Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

年份：2015

卷号：17

期号：14

起止页码：3580

外文期刊名：ORGANIC LETTERS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000358395500052)，CCR-EXPANDED(收录号:WOS:000358395500052)】；

基金：We are grateful for financial support from the National Basic Research Program of China (973-2015CB856600), the National Nature Science Foundation of China (21225210, 21421091, and 21472219), and the Science Technology Commission of the Shanghai Municipality (12ZR1453400). We thank Xiaojian Liu at Shanghai Institute of Technology for his initial studies on the project.

语种：英文

摘要：A mild and efficient method for copper-catalyzed trifluoromethylazidation and trifluoromethylthiocyanation of allenes was explored. A series of CF3-containing allyl azides and thiocyanates were obtained with high yields and good stereoselectivities, which can be used for further transformation to some valuable compounds.