文献类型：期刊文献

英文题名：Recent Progress of Metal Sulfide Photocatalysts for Solar Energy Conversion

作者：Zhu, Qiaohong[1];Xu, Qing[1];Du, Mengmeng[2];Zeng, Xiaofei[1];Zhong, Guofu[1];Qiu, Bocheng[2];Zhang, Jinlong[3]

机构：[1]Hangzhou Normal Univ, Coll Mat Chem & Chem Engn, Key Lab Organosilicon Chem & Mat Technol, Minist Educ, Hangzhou 311121, Zhejiang, Peoples R China;[2]Nanjing Agr Univ, Coll Sci, Dept Chem, Jiangsu Key Lab Pesticide Sci, Nanjing 210095, Peoples R China;[3]East China Univ Sci & Technol, Sch Chem & Mol Engn, Feringa Nobel Prize Scientist Joint Res Ctr, Lab Precis Chem & Mol Engn,Key Lab Adv Mat & Join, Shanghai 200237, Peoples R China

年份：2022

卷号：34

期号：45

外文期刊名：ADVANCED MATERIALS

收录：;EI(收录号：20224112867863);WOS:【SCI-EXPANDED(收录号:WOS:000865240400001)】；

基金：This work was supported by the National Key R&D Program of China (SQ2019YFE011329), National Natural Science Foundation of China (21972040), Natural Science Foundation of Jiangsu Province (BK20210382), Science and Technology Commission of Shanghai Municipality (2018SHZDZX03, 20DZ2250400), Innovation Program of Shanghai Municipal Education Commission (2021-01-07-00-02-E00106), the Program of Introducing Talents of Discipline to Universities (B16017, B20031), and the Fundamental Research Funds for the Central Universities. Q.Z. gratefully acknowledges the support from Hangzhou Normal University.

语种：英文

外文关键词：metal sulfides; photocatalysts; photocatalytic redox reactions; solar energy conversion; structure-activity relationship

摘要：Artificial photosynthetic solar-to-chemical cycles enable an entire environment to operate in a more complex, yet effective, way to perform natural photosynthesis. However, such artificial systems suffer from a lack of well-established photocatalysts with the ability to harvest the solar spectrum and rich catalytic active-site density. Benefiting from extensive experimental and theoretical investigations, this bottleneck may be overcome by devising a photocatalytic platform based on metal sulfides with predominant electronic, physical, and chemical properties. These tunable properties can endow them with abundant active sites, favorable light utilization, and expedited charge transportation for solar-to-chemical conversion. Here, it is described how some vital lessons extracted from previous investigations are employed to promote the further development of metal sulfides for artificial photosynthesis, including water splitting, CO2 reduction, N-2 reduction, and pollutant removal. Their functions, properties, synthetic strategies, emerging issues, design principles, and intrinsic functional mechanisms for photocatalytic redox reactions are discussed in detail. Finally, the associated challenges and prospects for the utilization of metal sulfides are highlighted and future development trends in photocatalysis are envisioned.