文献类型：期刊文献

英文题名：Amorphous nickel boride facilitates active site generation for HMF electrooxidation

作者：Wu, Yi Xiao[1];Xu, Hao Guan[1];Liu, Ji Kai[1];Jiang, Wenhan[2];Zhou, Yi[2];Zhang, Xin Yu[2];Liu, Peng Fei[1];Yang, Hua Gui[1]

机构：[1]East China Univ Sci & Technol, Sch Mat Sci & Engn, Key Lab Ultrafine Mat, Minist Educ, Shanghai 200237, Peoples R China;[2]East China Univ Sci & Technol, Sch Resources & Environm Engn, Dept Energy & Chem Engn, Shanghai 200237, Peoples R China

年份：2025

卷号：61

期号：49

起止页码：8943

外文期刊名：CHEMICAL COMMUNICATIONS

收录：;EI(收录号：20252118476120);WOS:【SCI-EXPANDED(收录号:WOS:001491695800001)】；

基金：This work was financially supported by the National Natural Science Foundation of China (22379043 and 22309053), the Science and Technology Commission of Shanghai Municipality (23YF1408500) and the Fundamental Research Funds for the Central Universities.

语种：英文

外文关键词：Borides

摘要：In this study, we demonstrate an amorphous NiB(O) electrocatalyst for 5-hydroxymethylfurfural oxidation reaction (HMFOR). The distinctive amorphous structure of NiB(O) facilitates rapid reconstruction, accelerating HMFOR kinetics. NiB(O) exhibits a high current density of 300 mA cm-2 at a low potential of 1.44 V vs. RHE with a yield of 2,5-furanedicarboxylic acid (FDCA) exceeding 92% and a conversion rate approaching 100% during five cycles of HMFOR.